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中国精品科技期刊2020
王唯,王浩,匡映,等. 魔芋葡甘聚糖-明胶-淀粉气凝胶过滤材料的结构与性能研究[J]. 华体会体育,2021,42(15):48−55. doi: 10.13386/j.issn1002-0306.2020110163.
引用本文: 王唯,王浩,匡映,等. 魔芋葡甘聚糖-明胶-淀粉气凝胶过滤材料的结构与性能研究[J]. 华体会体育,2021,42(15):48−55. doi: 10.13386/j.issn1002-0306.2020110163.
WANG Wei, WANG Hao, KUANG Ying, et al. Study on Structure and Properties of Konjac Glucomannan-Gelatin-Starch Aerogels as Filtration Materials[J]. Science and Technology of Food Industry, 2021, 42(15): 48−55. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2020110163.
Citation: WANG Wei, WANG Hao, KUANG Ying, et al. Study on Structure and Properties of Konjac Glucomannan-Gelatin-Starch Aerogels as Filtration Materials[J]. Science and Technology of Food Industry, 2021, 42(15): 48−55. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2020110163.

魔芋葡甘聚糖-明胶-淀粉气凝胶过滤材料的结构与性能研究

Study on Structure and Properties of Konjac Glucomannan-Gelatin-Starch Aerogels as Filtration Materials

  • 摘要: 为取代难以降解、易造成环境污染且资源有限的合成有机过滤材料,本研究以魔芋葡甘聚糖、马铃薯淀粉等食源性成分为基材,经过溶胶-凝胶及冷冻干燥法制备出可生物降解的魔芋葡甘聚糖-明胶-淀粉气凝胶滤材,对其微观形貌、密度与孔隙率、力学性能和过滤性能进行表征,并优化配方为KGM、明胶、淀粉投料质量比=1:2:2。最优配方制得的KGS2气凝胶孔径均一,密度为0.0589 g/cm3,孔隙率达84.9%,抗压强度为848.34 kPa,过滤阻力为116 Pa,对粒径范围为1~10 μm的颗粒物过滤效率均在95%以上。室内土埋法测定失重率结果显示,KGS2气凝胶在温度为40 ℃、相对湿度为60%、土壤pH为8.0的环境中失重率最高,28 d后达100%;按ISO 14855-1-2012中方法测得KGS2气凝胶第62 d时生物降解率达78.1%;大鼠急性经口毒性试验显示,KGS2气凝胶LD50大于2.4 g/kg BW。以上实验结果证明,KGS2气凝胶兼具良好的机械性能、较低的过滤阻力和较高的过滤效率,为生物可降解材料,并具较高的生物安全性,其作为绿色环保的新型过滤材料极具应用潜能。

     

    Abstract: In order to replace the synthetic organic filtration materials which are difficult to degrade and cause environmental pollution and limited resources, the konjac glucomannan-gelatin-starch aerogels filter materials were prepared via sol-gel and lyophilization methods by using food derived ingredients such as konjac glucomannan and potato starch as raw materials. The micromorphology, density and porosity, mechanical properties and filtration properties of the aerogels were characterized, and the optimized formula was KGM, gelatin and starch with the mass ratio of 1:2:2. The KGS2 aerogels prepared by the best formula had uniform pore size, density of 0.0589 g/cm3, porosity of 84.9%, compressive strength of 848.34 kPa, resistance of 116 Pa, and the filtration efficiency of particles with particle size range was 1~10 μm more than 95%. The weight loss rate of the KGS2 aerogels measured by indoor soil burying method showed that KGS2 aerogels had the highest weightlessness rate in the environment with temperature of 40 ℃, relative humidity of 60%, soil pH value of 8, and reached 100% after 28 days. According to the method in standard ISO 14855-1-2012, the biodegradation rate of the KGS2 aerogels was 78.1% on the 62th day. The acute oral toxicity test showed that the LD50 of KGS2 aerogels was more than 2.4 g/kg BW. The above experimental results show that KGS2 aerogel has good mechanical properties, low filtration resistance and high filtration efficiency. It is a biodegradable material with high biosafety. It has great potential as a new type of filtering material for environmental protection.

     

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